Ancient People Were No Dummies!
Researchers at Massachusetts Institute of Technology
have discovered that people in Mexico and Central America were making
modern-type rubber 3,500 years ago. They were ahead of Charles Goodyear and his
vulcanization process by thousands of years. In its natural state, gummy natural
rubber latex is not of much use. Goodyear discovered that sulfur could be used
to convert gummy natural latex into bouncy rubber. Sulfur causes cross-linking
of polymer molecules in natural latex and it is cross-linking that gives modern
rubber it's bounciness.
Samples of 3,500-year-old rubber balls which
had been preserved in a swamp were analyzed at Massachusetts Institute of
Technology. Results were published in the June 18th, issue of - Science
(website). Rubber in the ancient balls was cross-linked just as is modern
rubber. When sixteenth-century Spanish invaders came, they were amazed at the
bounciness of the rubber balls made by the natives. Ancient rubber-making
techniques had been passed down from generation to generation. Natives mixed
juice from morning glory vines with natural latex, producing bouncy rubber. Now
researchers have found that sulfur compounds in the juice of the morning glory
vine can cause cross-linking, just as the modern vulcanization process
does.
One reason the sixteenth century Spanish invaders
were so impressed with the rubber balls from Central America and Mexico was that
European balls of the time were not nearly so bouncy. European balls of the time
often consisted of pigskin filled with feathers, a far less bouncy item.